Progress and Prospects of Nanostructured Superhard Materials
In superhard materials research, two topics are of central focus. One is to understand hardness microscopically and to establish hardness models with the parameters calculated by first principles calculation, which can be used to guide the design or prediction of novel superhard crystals. The other is to synthesize superhard polycrystalline materials with enhanced comprehensive performance (i.e., hardness, fracture toughness, and thermal stability), with the ambition of achieving bulk materials harder than natural diamond. In this talk, I will discuss the microscopic hardness models of covalent crystals and its generalization to polycrystalline covalent materials. After that, I will discuss the nanotwinning approach for high-performance superhard materials, with special focus on nanotwinned cBN and diamond. I will conclude this talk with a discussion of challenges and future developments in superhard materials.